Highly Regio- and Stereoselective Hydrogermylation of Fluorinated Alkyl Propiolate - Physico-chimie des Matériaux et des Electrolytes pour l'Energie Laboratoire - - EA 6299 Accéder directement au contenu
Article Dans Une Revue SynOpen Année : 2019

Highly Regio- and Stereoselective Hydrogermylation of Fluorinated Alkyl Propiolate

Résumé

The selective introduction of fluoroalkylated vinylmetals in controlled strategies is a challenging process for many chemists. This study reports the highly regio- and stereoselective synthesis of functionalized vinylgermanes bearing a perfluoroalkyl group from per­fluoroalkylated acetylenic esters via AlCl3-catalyzed hydrogermylation. Regio- and stereoselectivity are highly dependent on the nature of the catalyst and the nature of the fluoroalkyl group of alkyne.

Dates et versions

hal-02056996 , version 1 (05-03-2019)

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Citer

Ranin. Kawtharani, Mirvat Elmasri, Khalil Cherry, Johan Jacquemin, Mohamed Abarbri. Highly Regio- and Stereoselective Hydrogermylation of Fluorinated Alkyl Propiolate. SynOpen, 2019, 03 (01), pp.4-10. ⟨10.1055/s-0037-1611666⟩. ⟨hal-02056996⟩

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