para-Azaquinodimethane based quinoidal polymers for opto-electronic applications: Impact of donor units on opto-electronic properties - Physico-chimie des Matériaux et des Electrolytes pour l'Energie Laboratoire - - EA 6299 Accéder directement au contenu
Article Dans Une Revue Materials Advances Année : 2022

para-Azaquinodimethane based quinoidal polymers for opto-electronic applications: Impact of donor units on opto-electronic properties

Résumé

para-azaquinodimethane (p-AQM) based quinoidal-donor (Q-D) alternating copolymers offer a unique opportunity to investigate the properties of quinoidal polymers. It was however reported that the bandgap increases with increasing number of donor aryl units, as a result of a weakening of the quinoidal character in the polymer backbone. To overcome this issue, herein two new polymers were designed and synthesized by incorporating fused donor (PAQM2T-TT) and vinylene linker (PAQM2T-TVT) units, following a strategy of enhanced backbone planarity. The thiophene-containing polymers PAQM3T and PAQM4T were also synthesized for better understanding of the influence of structural variations. Thus, in comparison with PAQM3T and PAQM4T, PAQM2T-TT and PAQM2T-TVT exhibited slight red shift in spite of having more extended donor units, which is consistent with enhanced planarity and quinoidal character as suggested by DFT calculations. It is also found that the different donor units have a limited impact on the HOMO energy level of the p-AQM copolymers. Transport properties are measured by field effect transistors, and the photovoltaic properties of these p-AQM based polymers are reported for the first time, as electron donor materials in inverted configuration devices. PAQM2T-TVT containing thiophene vinylene thiophene comonomer exhibits planar structure leading to a hole mobility of 3.8×10-2 cm-2 V s-1. When combined with a fullerene acceptor in solar cells, PAQM2T-TVT polymer exhibited a highest PCE of 2.32%.

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Chimie
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Dates et versions

hal-03795491 , version 1 (04-10-2022)

Identifiants

  • HAL Id : hal-03795491 , version 1

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Bharath Dyaga, Sasikumar Mayarambakam, Olzhas A Ibraikulov, Nicolas Zimmermann, Sadiara Fall, et al.. para-Azaquinodimethane based quinoidal polymers for opto-electronic applications: Impact of donor units on opto-electronic properties. Materials Advances, 2022. ⟨hal-03795491⟩
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